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Both domains are indeed resolving to the same IP address: 82.148.225.141. My bet is that either the headers for the www address are not setup to resolve to the correct website in IIS.
As TT_Mark mentioned, his is very easily corrected with access to the IIS server. I would add however that the correct procedure would be to perform a 301 redirect on one of those domains (pointing it to the other). So http://schottremovals.co.uk resolved to http://www.schottremovals.co.uk or visa versa. This will prevent issues with users, logins, cookies bookmarks, etc and also theoretically help your SEO as Google can see duplicate content on two domains. It’s also good practice to 301 all domains to a “primary” domain for these reasons.
Here is a god article on the process: http://www.webpronews.com/topnews/2005/09/28/how-to-set-up-a-redirect-on-iis-nonwww-domain-name-to-www-domain-name